Dark red crystal meso-5,10,15,20-tetra (p-aminophenyl) cobalt porphyrin (co TAPP); Meso-5,10,15,20-tetra (p-aminophenyl) cobalt porphyrin no complex (TAPP co no) supplied by Qiyue

meso-5,10,15,20- Four ( P-aminophenyl ) Cobalt porphyrin (Co-TAPP)

Weighing equal quantities of substances H2TAPP And cobalt acetate in an agate mortar ,3540℃ Grind in a sand bath

30min, Dropping ligand mass 5% Acetone , Continue grinding 30min, Transfer the reactant with methanol , Upper silica gel column , Elute with absolute ethanol , Collect a ribbon , Steam dry under reduced pressure ,40℃ Vacuum drying , Get dark red crystals meso-5,10,15,20- Tetra aminophenyl cobalt porphyrin (2)(Co-TAPP), Yield 79.4%.

meso-5,10,15,20- Four ( P-aminophenyl ) Cobalt porphyrin -NO Complexes (TAPP-Co-NO)

Weighing Co-TAPP100mg, Soluble in 30mL acetone , in 50mL In a three necked flask , Argon gas is introduced into the bottle mouth for protection , The middle bottle mouth is inserted with NO Connect the air duct of the generator to the liquid level , The other bottle mouth leads the tail gas to the absorption bottle which is successively connected with saturated potassium permanganate solution and sodium hydroxide solution . First direction NO Generator ( from NaNO2 The aqueous solution is added dropwise H2SO4 Generate NO) and Co-TAPP The container is filled with argon 2h, Remove the oxygen from the flask , Then stop going NO Argon gas is introduced into the occurrence bottle , Open the piston of constant pressure dropping funnel , Drop sulfuric acid into the flask , Generate NO Gas is introduced Co-TAPP In a solution of , Room temperature reaction 2h after , Evaporate the solvent under reduced pressure to obtain dark red crystals meso-5,10,15,20- Tetra aminophenyl cobalt porphyrin -NO Complexes 3(TAPP-Co-NO), Yield 83.8%

 

  Porphyrin catalogue ：
  [email protected] Organic inorganic composite nanoparticles
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This article comes from Xi'an Qiyue biology Xiaobian axc