Bright purple crystal meso tetra (4-aminophenyl) porphyrin tapp/tapppt/tappco/tappcd/tappzn/tapppd/tappcu/tappni/tappfe/tappmn metal complex - supplied by Qiyue

Bright purple crystal meso Four (4- Aminophenyl ) porphyrin TAPP Introduction to

8gTNPP(10.0mmol) Soluble in 280mL Concentrated hydrochloric acid , At room temperature 30min In addition 30g hydration SnCl2(132.5mmol) And 80mL A mixture of concentrated hydrochloric acid , Stirring reaction 2.5h, Heat up to 65~70℃ reaction 40min, After natural cooling , Put it in the refrigerator at low temperature overnight . The next day , Collect solids by suction filtration , Disperse the resulting solid in 500mL in the water , Neutralize with concentrated ammonia water until pH The value is 8~9, Suction filtration , Wash the separated purple black solid with methanol until the filtrate is colorless . After drying the above purple black solid mixture , use 500mL Chloroform extraction , Spin dry the solvent , After recrystallization , Bright purple TAPP Crystal 2.33g(3.45mmol), Yield 34.5%.

 

 

  Porphyrin custom products ：

5-(4-3- Cyanobenzoyl benzoate Amino group ) phenyl -101,5,20- Triphenylporphyrin ligand (CBTPPH2)
5,10,15,20- Four （4- Octyl aminophenyl ） porphyrin ( abbreviation TOAPP） 5,10,15,20-tetra(4-octanoylamidophenyl)porphyrin
5,10,15,20- Four (4- Octadecylamidophenyl ) porphyrin (TO18APP)
5,10,15,20- Four （4- Decyl aminophenyl ） porphyrin ( abbreviation TDAPP) 5,10,15,20-tetra(4-decanoylamidophenyl)porphyrin
5,10,15,20- Four （4- Lauryl aminophenyl ） porphyrin ( abbreviation TLAPP) 5,10,15,20-tetra(4-lauroylamidophenyl)porphyrin
5,10,15,20- Four （4- Palmitoyl aminophenyl ） porphyrin ( abbreviation TPAPP) 5,10,15,20-tetra(4-palmylamidophenyl)porphyrin
5,10,15,20- Four （4- Theacylaminophenyl ） porphyrin ( abbreviation TSAPP）5,10,15,20-tetra(4-tearylamidophenyl)porphyrin
Azo bonded conjugated copper porphyrin polymers (CuⅡ-APP)
Tetraiodide (4- Trimethylaminophenyl ) porphyrin (TTMAPPI)
Four (4- Trimethylaminophenyl ) Porphyrin Hydroxide (TTMAPPOH)
α,α,α,β- Four -[ adjacent ( Tert butoxycarbonylalanine ) Aminophenyl ] porphyrin H2T(o-BocAla)APP
α,α,α,β- Four -[ adjacent ( Tert butoxycarbonylalanine ) Aminophenyl ] Porphyrin zinc (Ⅱ) Complexes ZnT(o-BocAla)APP(Zn-1)
α,α,α,β- Four -[ adjacent ( Tert butoxycarbonylthreonine ) Aminophenyl ] porphyrin H2T(o-BocThr)APP
α,α,α,β- Four -[ adjacent ( Tert butoxycarbonylthreonine ) Aminophenyl ] Porphyrin zinc (Ⅱ) Complexes ZnT(o-BocTyr)APP(Zn-3)
Tetraiodide -(4- Trimethylamine phenyl ) porphyrin (TTMAPPIH2) modification n-GaAS
Four 〈N,N_ Diphenyl p-amino ) Phenylporphyrin (TDPaPPH2) Red fluorescence
Bromination — Four (N— Cetyl ) P-isonicotinamide phenylporphyrin (THIAPPBr)
 

  This article comes from Xiaobian axc Xi'an Qiyue .2022.02.14