Meso tetra (4-bromophenyl) porphyrin (tbpp); 5,10,15,20-tetra (4-methoxy-3-sulfonylphenyl) porphyrin [t (4-mop) ps4] supplied by Qiyue

meso- Four (4- Bromophenyl ) Porphyrin (TBPP)

Adopt Improvement "Alder Law ", Pyrrole and p-bromobenzaldehyde are used as raw materials , Synthesized meso- Four (4- Bromophenyl ) porphyrin (TBPP), Its structure and performance have been UV-Vis,FL and IR characterization . The dosage of nitrobenzene was studied , Solvent consumption , Solvent concentration , Feed ratio η[n( P-bromobenzaldehyde )/n( pyrrole )] And reaction time TBPP Effect of yield . It turns out that : Under good reaction conditions [ pyrrole 25mmol,η=1.05/1, Propionic acid 70mL, nitrobenzene 2mL, Solvent concentration 30mL, Reflux reaction 40min] Next ,TBPP yield 30.68%.

5,10,15,20- Four (4- Methoxy -3- Phenyl sulfonate ) porphyrin [T(4-MOP)PS4]

T(4-MOP)P Synthesis : The method of referring to literature , On 500mL Add... To the three necked bottle 200mL Propionic acid , Heat until slightly boiling , Quick drip 13.4mL(0.11mol) Anisaldehyde and 7.0mL(0.10mol) Freshly distilled pirio and 80mL A mixture of propionic acid . Slight heat reflux 30min, Cool naturally to room temperature under stirring . Suction filtration . Wash thoroughly with ethanol 、 Get purple crystal . Distill the mother liquor under reduced pressure . Remove some propionic acid , After crystallization , cooling , Suction filtration , Some products are also available . Total yield 22%.

  Porphyrin catalogue ：

meso- Four -( Yes - Hydroxybenzene ) porphyrin ( abbreviation T-4-HPP)
Temperature sensitive star porphyrin based block copolymer (THPP-(PNIPAM-b-POEGMA)4)
[email protected] Core shell composite
Phenylporphyrin functionalized glycidyl methacrylate (PP-PGMA)
Hydroxyl phenyl porphyrin functionalized glycidyl methacrylate (HPP-PGMA)
Tetrahydroxyphenyl metalloporphyrin (MTHPP)/TiO2
Zinc sensitized tetraphenylporphyrin TNTs(TNTs-ZnTPP)
5,10,15,20- Four -(3- Methoxy -4- Hydroxyphenyl ) Porphyrin cobalt (CoTMHPP)
Albumin based metalloporphyrin complex photosensitizer (BSA-ZnTpHPP、BSA-ZnToHPP、BSA-ZnTmMpHPP)
Water soluble biopolymer metalloporphyrin complexes (BSA-ZnTpHPP、BSA-ZnToHPP、BSA-ZnTmMpHPP),
Four ( P-isopropyl phenyl ) porphyrin (H2TIPP)
5,10,15,20- Four (4-(1- Imidazolyl ) phenyl ) porphyrin (H(2)tipp)
5-( M-carbonylbenzoic acid )- Aminophenyl -10,15,20- Triphenyl porphyrin (m-CPTPP)
5-( M-carbonylbenzoic acid )- Aminophenyl -10,15,20- Triphenylporphyrin zinc (Zn-CPTPP)
5-( M-carbonylbenzoic acid )- Aminophenyl -10,15,20- Copper triphenylporphyrin (Cu-CPTPP)
5-( M-carbonylbenzoic acid )- Aminophenyl -10,15,20- Triphenyl porphyrin iron (Fe-CPTPP)
  
This article comes from Xi'an Qiyue biology Xiaobian axc