Tetradecanoxy tetraphenylporphyrin methacrylate mm-tpp-14c; Cetanoxy tetraphenyl porphyrin methacrylate mm-tpp-16c; Purple solid; Qiyue supply

. Tetradecyl oxytetraphenyl porphyrin methacrylate (MM-TPP-14C) Introduction to

Under ice bath conditions , Add... In a single mouthed bottle 1.5g(0.0012mol) Monohydroxytetraalkoxyphenyl , Add refined tetrahydrofuran 250ml stir , Then add the refined triethylamine 1.65ml, take 0.92ml Methacryloyl chloride is soluble in 40ml Refined tetrahydrofuran , Slowly drop into the reaction system . reaction 24h. Suction filtration , Spin the filtrate dry , Dichloromethane dissolves , Dilute in turn HCl solution 、 rare NaOH solution 、 Wash with distilled water . Anhydrous magnesium sulfate drying , Filter , After the solvent is evaporated dry , Separate with silica gel column , Chloroform as eluent , Collect a component , After spin drying , It is purple solid methacrylic acid Dodecyloxy tetraphenyl (MM-TPP-14C). The yield is 65%.

Cetyloxy tetraphenyl porphyrin methacrylate (MM-TPP-16C) The preparation method of

Under ice bath conditions , Add... In a single mouthed bottle 1g(0.0007mol) Monohydroxy hexadecanoxyphenyl , Add refined tetrahydrofuran 250ml stir , Then add the refined triethylamine 1.27ml, take 0.7ml Methacryloyl chloride is soluble in 40ml Refined tetrahydrofuran , Slowly drop into the reaction system . reaction 24h. Suction filtration , Spin the filtrate dry , Dichloromethane dissolves , Dilute in turn HCI solution 、 rare NaOH solution 、 Wash with distilled water . Anhydrous magnesium sulfate drying , Filter , After the solvent is evaporated dry , Separate with silica gel column , Chloroform as eluent , Collect a component , After spin drying , It is purple solid hexadecanoxy tetraphenyl porphyrin methacrylate (MM-TPP-16C). The yield is 68%.

  Porphyrin catalogue ：
  meso- Four (4- Aminophenyl ) porphyrin (TAPP)
meso- Four [ Yes -(P-N- Carbazole benzylidene imino )] Phenylporphyrin (TCIPP)
Porphyrin ligands - Tetracyano porphyrin Cu-CNTCPP and Zn-CNTCPP
Tetraphenylporphyrin iron chloride (TPPFeCl)
Chlorotetra-o-chlorophenyl porphyrin iron (TCPPFeCl)
Tetrapyridyl copper porphyrin (CuTPyP) Single crystal two-dimensional nanosheets
Tetrapyridyl zinc porphyrin (ZnTPyP)
Y-TCPP Polygonal nanosheets
Eu-TCPP Nanoparticles / Square nano sheet
meso- Four (4- Phenyl sulfonic acid ) porphyrin (TSPP)

Four ( Carboxyphenyl ) Porphyrin palladium (Pd-TCPP)
Metal organic frame wrapped porphyrin material [email protected]
PCN-777 The parcel 5,10,15,20- Four (4- Carboxyphenyl ) Manganese porphyrin (Mn-TCPP) Wrapping type of MOFs material [email protected]
meso Four (4 Sulfophenyl ) porphyrin (TPPS)
Four (4- Carboxyphenyl ) Manganese porphyrin [Mn TCPP]
Four (4- Carboxyphenyl ) Cobalt porphyrin [CoTCPP]
Four (4- Carboxyphenyl ) Iron porphyrin [Fe TCPP]
Tetracarboxyphenyl porphyrin (TCPP) Water soluble fluorescent probe (PEI-TCPP)
5,10,15,20- Tetracyano porphyrin ligand (H2CNTCPP)
meso- Four (4- Nitro ) Phenylporphyrin (TNPP)
meso- Four (4- Aminophenyl ) porphyrin (TAPP
This article comes from Xi'an Qiyue Xiaobian axc.222.02.17