BOC protected alanine porphyrin compound TAPP ala BOC BOC BOC protected phenylalanine porphyrin compound TAPP Phe BOC Qi Yue supply

BOC Protected alanine porphyrin compounds TAPP-Ala-BOC The preparation method of

take 0.893gBOC Protected alanine (Boc-L-Ala,4.72mmol),1.22gDCC(5.94mmol),0.036gDMAP(0.495mmol) Mixed in 100mL In a round bottom flask , Join in 15mL Dehydration grade dichloromethane as solvent ,6℃ Under airtight mixing 1h, Then add 0.10gTAPP(0.148mmol),6℃ Under airtight mixing 72h, The mixture obtained from the reaction is filtered , The filtrate is rotated and evaporated to remove the solvent , Dark red powder . After recrystallization and purification of this liquid with ethyl acetate at low temperature , With ethyl acetate / Petroleum ether (4/1,v/v) The mixed solvent is used for column chromatography separation , Collect dark red components , Get the product 180.8mg, Yield 90.0%.

 

 BOC Protect phenylalanine porphyrin compounds TAPP-Phe-BOC Of Characterization map

 

  Porphyrin custom product catalog :

5-(2-[4-(N- Imidazolyl ) Butylamide Group ] phenyl }-10,15,20- Triphenyl porphyrin
5-{2-[5-(N- Imidazolyl ) Amylamido ] phenyl }-10,15,20- Triphenyl porphyrin
5-(2- Hydroxyphenyl )-10,15,20- Triphenyl porphyrin
5-(4- Hydroxyphenyl )-10,15,20- Triphenyl porphyrin
5-[2-(4- Bromobutoxy ) phenyl ]-10,15,20- Triphenyl porphyrin
5-[2-[4-(1- Imidazolyl ) Butoxy ] phenyl }-10,15,20- Triphenyl porphyrin
5-{4-[4-(2- Mercaptobenzothiazole ) Butoxy ] phenyl }-10,15,20- Triphenyl porphyrin
5-(4- Cetyloxyphenyl )-10,15,20- Triphenyl porphyrin
Cobalt Tetraphenylporphyrin (CoTPP)-Au/C Composite catalyst
Succinic anhydride modified tetra aminophenyl porphyrin derivatives TA4C
Graphene oxide modified hydroxypropyl -p- Cyclodextrin adsorbs tetraphenylporphyrin (HP-β-CD-GO/TPP)
Porphyrin modified carbon nanotube composites
5-(4- Hydroxyphenyl )-10, 15- Two (4- Sodium sulfonate phenyl )-20- Phenyl porphyrin modified carbon nanotube composites (HSPP/CNTs)
5-(4- Hydroxyphenyl )-10, 15, 20- 3、 ... and (3- Nitrophenyl ) Porphyrins and their chemically modified carbon nanotube complexes
Four -(4- Sodium sulfonate phenyl ) porphyrin (TPPS4) Modified carbon nanotube composites （TPPS4/CNTs）
TPPS4 Porphyrin modified carbon nanotubes
THPP/NiO Nanocomposites
Tetrahydroxyphenyl porphyrin / Nickel oxide nanosheets (THPP/NiO） Nanocomposites
Tetracarboxyl group / Hydroxyphenyl porphyrins and transition metal oxides
TPPS- Plant esterase complex solution
Sulfonated tetraphenyl porphyrin - Plant esterase complex solution
Iron porphyrin functionalized microporous wall organic nanotube networks (Fe(TPP)Cl-MONNs)

This article comes from Xiaobian axc Xi'an Qiyue .2022.02.14