BOC protected amino acid porphyrins TAPP ala BOC, TAPP Phe BOC, TAPP Trp BOC, Zn · TAPP ala BOC, Zn · TAPP Phe BOC, Zn · TAPP Trp BOC Qiyue

This paper synthesized TAPP、TAPP-Ala-BOC、TAPP-Phe-BOC、TAPP-Trp-BOC、Zn·TAPP-Ala-BOC、Zn·TAPP-Phe-BOC、Zn·TAPP-Trp-BOC etc. 7 Porphyrins and their metallic zinc (Ⅱ) Complexes ,

We will be four (4- Aminophenyl ) Porphyrins are bound to amino acids by amide bonds , Connecting band tert butoxycarbonyl (BOC) Protective amino acids , It can recognize blood vessels around cells , Increased cell selectivity ; Band BOC Protective amino acids modify it , Avoid self aggregation in the human body , It can increase water solubility ; The metal atoms that pass through the central nucleus bind , Change the large absorption wavelength of porphyrin ring , So that it can penetrate deep tissues in treatment . The main research content of this paper ：(1) Series new with tert butoxycarbonyl (BOC) Protected amino acid porphyrins and their metals Zn(Ⅱ) Synthesis and characterization of compounds ;(2) For the new type with tert butoxycarbonyl (BOC) Protected amino acid porphyrins and their metals Zn(Ⅱ) Spectral properties of compounds （ Ultraviolet - Visible absorption spectrum 、 Fluorescence spectrum ） The study of .

BOC Exhibition of protected amino acid porphyrin products  

TAPP-Ala-BOC

TAPP-Phe-BOC

TAPP-Trp-BOC

Zn·TAPP-Ala-BOC

Zn·TAPP-Phe-BOC

Zn·TAPP-Trp-BOC

BOC Protected propyl amino acid porphyrin (TAPP-Ala-BOC)
BOC Protected phenylpropanoic acid porphyrin (TAPP-Phe-BOC)
BOC Protected color amino acid porphyrin (TAPP-Trp-BOC)
5,10,15,20- Four -[ Yes ( Tert butoxycarbonylthreonine ) Aminophenyl ] porphyrin (TAPP-Thr-Boc)
symmetry Boc- Threonine porphyrin spectral probe
meso- Four ( Yes - Methylpyridyl ) porphyrin (TMpyP-4)
(Boc- Threonine ) Aminophenyl ] porphyrin (TAPP-Thr-Boc)
meso- 3、 ... and (p- Trimethylammonium ) Phenylporphyrin (TMAPP)
meso- Four (4- Trimethylammonium phenyl )- porphyrin (H2TAPP)
meso- 3、 ... and ( Yes - Trimethylammonium ) Phenylporphyrin (TMAPP)

  This article comes from Xiaobian axc Xi'an Qiyue .2022.02.14