BOC protected phenylalanine zinc porphyrin (Zn · TAPP Phe BOC) / iron porphyrin (Fe · TAPP Phe BOC) / nickel porphyrin (Ni · TAPP Phe BOC) / manganese porphyrin (Mn · TAPP Phe BOC) Qiyue Keke

BOC Protected phenylalanine zinc porphyrin (Zn·TAPP-Phe-BOC)/ Iron porphyrin (Fe·TAPP-Phe-BOC)/ Nickel porphyrin (Ni·TAPP-Phe-BOC)/ Manganese porphyrin (Mn·TAPP-Phe-BOC) Qi Yue popular science

BOC Protected phenylalanine zinc porphyrin (Zn·TAPP-Phe-BOC,4b) And characterization （ Pink solid ） Introduction to

Abstract ： The invention discloses a preparation method of a novel porphyrin . With p-nitrobenzaldehyde , O-hydroxybenzaldehyde , Pyrrole as raw material , use Adler Synthesis of asymmetric benzene substituted porphyrins I, And then use BOC The protected phenylalanine is dissolved in dichlorosulfoxide , Add porphyrin after reflux reaction I Continue reflux reaction , obtain 5-(2- Tert butyloxyformic acid aminophenyl alanine phenyl )-10,15,20-(4- Nitrophenyl ) Chiral Porphyrins . This new porphyrin has chiral recognition ability , It will be used as an ideal framework to construct artificial receptors in the study of molecular recognition .

Porphyrin custom products ：

Cerium dioxide / Tetraaminophenyl porphyrin composite film (CeO2/TAPP)
Tetraphenyl porphyrin tetrasulfonic Acid (TPPs) Functionalized graphene oxide / Polyaniline complex (PGOT)
Tetracarboxyphenyl porphyrin / Indole composites (TCPP/Indol)
graphene @ Tetraphenyl porphyrin @ Gold Composites ([email protected]@Au)
Tetrahydroxyphenyl metalloporphyrin - Titanium dioxide composites (MTHPP/TiO2)
Zinc porphyrin molecularly imprinted polymer composite membrane (ZnTPP-MIP)
Tetrahydroxyphenyl porphyrin nanorods / Molybdenum disulfide nano sheet composite (THPP/MoS₂)
Tetrahydroxyphenyl porphyrin / Graphene oxide composites (GO/THPP)
5-(4- Cetyloxyphenyl )-10,15,20- Triphenyl porphyrin
5-(4- Cetylcarbonyloxyphenyl )-10,15,20- Triphenyl porphyrin
5-[4-(α Anthraquinone imide ) Methoxyphenyl ]-10,15,20- Triphenyl porphyrin
5-{4-[5-(2,4,6- Trinitrobenzene oxygen ) Acetaminophen -1- Anthraquinone imine ] Formoxyphenyl }-10,15,20- Triphenyl porphyrin
5-(2- Hydroxyphenyl )-10,15,20- 3、 ... and (4- Methyl phenyl ) porphyrin
5-(2- Bromoethoxyphenyl )-10,15,20- 3、 ... and (4- Methyl phenyl ) porphyrin
5-(2- Bromopropoxy phenyl )-10,15,20- 3、 ... and (4- Methyl phenyl ) porphyrin
5-{2-[( Benzo -15- crown -5)-4- amino ] Ethoxyphenyl }-10,15,20- 3、 ... and (4- Methyl phenyl ) porphyrin
5- M-hydroxyphenyl -10,15,20- Three p-methoxyphenyl porphyrins
5-( 3- Acetoxyphenyl )-10,15,20- 3、 ... and (4- Methoxyphenyl ) porphyrin
5-(4- Hydroxyphenyl )-10,15,20- Three p-methoxyphenyl porphyrins
5-[ 4-(α- Anthraquinone imide ） Methoxyphenyl ]-10,15,20- Three p-methoxyphenyl porphyrins

 
  This article comes from Xiaobian axc Xi'an Qiyue .2022.02.14